Laser Doping

 

 

Contact: Francesca Chiodi

Laser Doping Principles

In the Pulsed Laser Induced Epitaxy, or PLIE technique, the transient surface melting of Silicon induced by a laser pulse of duration ~ 10 ns takes place over a thickness of some 10 nm allows a rapid mixing of the atoms of different nature in the molten zone. The ensuing rapid crystalisation  - at a velocity of a few m/s – initiates at the boundary with the underlying crystal, and leads to a stable material. Preliminary modification of chemical surface bonds (through chimisorbtion) allows one to adjust the energy balance and the desorption or incorporation of surface ad atoms. The introduction of such new atomic species can be done before laser treatment through deposition or implantation, or during the treatment through the exposure of the surface to a gaseous atmosphere or chemisorbed layer. One then speaks of Gas Immersion Laser Doping or GILD. These processes allow one to obtain samples the chemical composition of which is inaccessible by other means

Applications of laser treatment: GILD and PLIE

The very low energy input to the surface allows one to act without deteriorating the underlying material structure. This structure can be under strong strain, which allows applications in strain engineering for microelectronics and other microtechnologies. 

Application to micro-nanoresonators (in collaboration with C2N – MiNaSys)

As a result of strain engineering, the resonance frequency of a Silicon nanobridge can be enhanced by up to a factor 40 after GILD. Artificially induced strains can amount up to 4 GPa. 

Example of a 120 nm wide nanobridge (left hand panel, SEM image) and resonance frequencies of the nanobridge for different doping levels, lengths, and thicknesses (right hand panel). 

Application to the modification, by strain, of the and structure of Germanium by phosphorus doping

Ambient temperature luminescence spectra of bulk Germanium (left hand panel) and GeOI (right hand panel) after GILD Phosphorus doping. The detector is limited to the wavelength range below 1590 nm.

 

Publications (since 2018)

  • Chiodi, F. , Bayliss, S.L.,  Barast, L., Débarre, D.,  Bouchiat, H., Friend, R.H., Chepelianskii, A.D., Room temperature magneto-optic effect in silicon light-emitting diodes, Nature Communications 9, 1 December 2018, Article # 398  - https://hal.archives-ouvertes.fr/hal-02399933v1 

People

  • Franscesca Chiodi
  • Dominique Debarre
  • Géraldine Hallais

Collaborations

  • At C2N
    • MiNaSys
  • In France
    • NAEL

Fundings